Winklaus,
I wasn't going to reply to this, not because I didn't want to help, but because I really don't have a good answer for you!
Its kind of like asking a mechanic, "how did you learn how to fix cars?" You'll find that almost all of them had a passion for cars and... well, just tinkered! Once you start tinkering, you start asking specific questions and are able to search online. If you ask "how do I fix cars", you won't get a good response because it's just too broad. If you ask "my car does _this_ when it's idle, what could be wrong?" and you'll get better hits.
So..um..that's why I didn't want to respond, because I'm not really helping you out here
And it's much easier to learn by doing when there's something specific you're trying to do. So, perhaps we can start by doing that.
To start playing with your XO, just, well, push buttons! See what happens! You mentioned something about changing settings. What settings do you want to change?
Caliban1 wrote:I'm especially interested in going from Sugar to Python
I'm not sure what you mean by that. Sugar is to Python, as Windows is to Visual Basic (omg, what a horrible analogy.. /shoot self. I can't believe I just compared python to vb.). You don't "go from windows to vb".
If you want to start programming in python and play around, the Pippy Activity is what you're looking for.